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• W2083789916 abstract "The influence of the residual growth catalyst on the reducibility and catalytic activity of Pt nanoparticles supported on oxygen- and nitrogen-functionalized CNTs (OCNTs and NCNTs) was systematically investigated. It was found that the presence of the residual growth catalyst significantly influenced the oxygen and nitrogen functionalization of CNTs, which consequently altered the reducibility of the supported Pt nanoparticles. Pt nanoparticles on NCNTs showed a higher stability against sintering in reducing atmosphere at 200 °C and 400 °C than those on OCNTs. On NCNTs, Pt was in a higher oxidation state and was not as easily reducible as on OCNTs. In hydrogenation catalysis, removing the residual growth catalyst is essential for the supported Pt catalyst to achieve a better performance. Compared with Pt on OCNTs, Pt on NCNTs was less active, but more selective in olefin hydrogenation due to the poisoning effect of the surface nitrogen species." @default.
• W2083789916 created "2016-06-24" @default.
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• W2083789916 creator A5026930069 @default.
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• W2083789916 date "2013-11-01" @default.
• W2083789916 modified "2023-10-10" @default.
• W2083789916 title "The influence of the residual growth catalyst in functionalized carbon nanotubes on supported Pt nanoparticles applied in selective olefin hydrogenation" @default.
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• W2083789916 doi "https://doi.org/10.1016/j.jcat.2013.06.030" @default.
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