Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083792277> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W2083792277 endingPage "2813" @default.
- W2083792277 startingPage "2808" @default.
- W2083792277 abstract "Reduction of 2′,4′,6′-trimethyl-2-nitrobiphenyl by triethyl phosphite gives 2-amino-2′,4′,6′-trimethylbiphenyl and triethyl N-(2′,4′,6′-trimethylbiphenyl-2-yl)phosphorimidate. The same reduction, carried out in cumene or in t-butylbenzene gives, additionally, 8,10-dimethylphenanthridine, and, in cumene, 2,3-dimethyl-2,3-diphenyl-butane, indicating the intermediacy of a triplet nitrene. Reduction of nitrobenzene by diethyl methylphosphonite in an excess of diethylamine gives 2-diethylamino-3H-azepine (83%), while the corresponding reaction with 2-nitrobiphenyl gives 2-diethylamino-3-phenyl-3H-azepine (13%) in addition to carbazole (63%), pointing to an intermediate similar to that present in decompositions of azides, i.e. a nitrene or nitrenoid species, the nature of which is discussed." @default.
- W2083792277 created "2016-06-24" @default.
- W2083792277 creator A5031737258 @default.
- W2083792277 creator A5086846328 @default.
- W2083792277 date "1969-01-01" @default.
- W2083792277 modified "2023-10-09" @default.
- W2083792277 title "Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part IV. Mechanistic aspects of the reduction of 2,4,6-trimethyl-2′-nitrobiphenyl, 2-nitrobiphenyl, and nitrobenzene" @default.
- W2083792277 doi "https://doi.org/10.1039/j39690002808" @default.
- W2083792277 hasPublicationYear "1969" @default.
- W2083792277 type Work @default.
- W2083792277 sameAs 2083792277 @default.
- W2083792277 citedByCount "34" @default.
- W2083792277 countsByYear W20837922772012 @default.
- W2083792277 countsByYear W20837922772014 @default.
- W2083792277 countsByYear W20837922772016 @default.
- W2083792277 countsByYear W20837922772017 @default.
- W2083792277 countsByYear W20837922772018 @default.
- W2083792277 countsByYear W20837922772019 @default.
- W2083792277 countsByYear W20837922772020 @default.
- W2083792277 countsByYear W20837922772021 @default.
- W2083792277 countsByYear W20837922772022 @default.
- W2083792277 countsByYear W20837922772023 @default.
- W2083792277 crossrefType "journal-article" @default.
- W2083792277 hasAuthorship W2083792277A5031737258 @default.
- W2083792277 hasAuthorship W2083792277A5086846328 @default.
- W2083792277 hasConcept C155647269 @default.
- W2083792277 hasConcept C161790260 @default.
- W2083792277 hasConcept C178790620 @default.
- W2083792277 hasConcept C185592680 @default.
- W2083792277 hasConcept C2777691172 @default.
- W2083792277 hasConcept C2778215507 @default.
- W2083792277 hasConcept C2780809723 @default.
- W2083792277 hasConcept C2909807293 @default.
- W2083792277 hasConcept C38489247 @default.
- W2083792277 hasConcept C40875361 @default.
- W2083792277 hasConcept C75473681 @default.
- W2083792277 hasConceptScore W2083792277C155647269 @default.
- W2083792277 hasConceptScore W2083792277C161790260 @default.
- W2083792277 hasConceptScore W2083792277C178790620 @default.
- W2083792277 hasConceptScore W2083792277C185592680 @default.
- W2083792277 hasConceptScore W2083792277C2777691172 @default.
- W2083792277 hasConceptScore W2083792277C2778215507 @default.
- W2083792277 hasConceptScore W2083792277C2780809723 @default.
- W2083792277 hasConceptScore W2083792277C2909807293 @default.
- W2083792277 hasConceptScore W2083792277C38489247 @default.
- W2083792277 hasConceptScore W2083792277C40875361 @default.
- W2083792277 hasConceptScore W2083792277C75473681 @default.
- W2083792277 hasIssue "20" @default.
- W2083792277 hasLocation W20837922771 @default.
- W2083792277 hasOpenAccess W2083792277 @default.
- W2083792277 hasPrimaryLocation W20837922771 @default.
- W2083792277 hasRelatedWork W192314787 @default.
- W2083792277 hasRelatedWork W1976568430 @default.
- W2083792277 hasRelatedWork W2024851977 @default.
- W2083792277 hasRelatedWork W2028639891 @default.
- W2083792277 hasRelatedWork W2054939064 @default.
- W2083792277 hasRelatedWork W2060951519 @default.
- W2083792277 hasRelatedWork W2065267492 @default.
- W2083792277 hasRelatedWork W3160866726 @default.
- W2083792277 hasRelatedWork W2036283808 @default.
- W2083792277 hasRelatedWork W2478427552 @default.
- W2083792277 hasVolume "0" @default.
- W2083792277 isParatext "false" @default.
- W2083792277 isRetracted "false" @default.
- W2083792277 magId "2083792277" @default.
- W2083792277 workType "article" @default.