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- W2083811034 abstract "(−)-Tabersonine 4 was submitted to quaternization and Emde degradation to yield the 3,4-seco derivative 5, which was hydrolyzed and decarboxylated to the diastereomeric indolenines 8 and 9. Oxidative rearrangement of 8 and 9 yielded the two diastereomeric seco-rhazinilams (−)-10 and (+)-11, differing in the atropomeric conformations of their biarylic system. The results are discussed in the realm of oxidation and rearrangements in the aspidosperma series of indole alkaloids." @default.
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- W2083811034 date "1997-12-01" @default.
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- W2083811034 title "The synthesis of two diastereomeric seco-rhazinilams with opposite atropomeric chiralities" @default.
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