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- W2083875490 abstract "Cation−anion interactions in 2-propanol solutions of sodium salts NaY (Y = MeS, iPrS, tBuS, iPrO, SCN, ClO4, Ph4B) have been studied by 23Na-NMR spectroscopy. The analysis involved measurements of chemical shift and T1 as a function of salt concentration in both the absence and presence of the Na+-complexing agent 18-crown-6. The results indicate that the interactions of Na+ with alkoxides and thiol anions are very different from those with charge-delocalized anions (SCN−, ClO4−, Ph4B−), and that the degree of association in NaSR salts is greater for R = tBu than for R = Me." @default.
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- W2083875490 date "2000-05-01" @default.
- W2083875490 modified "2023-09-27" @default.
- W2083875490 title "Investigation of Cation−Anion Interactions in 2-Propanol Solutions of Sodium Alkoxides and Thiolates by23Na-NMR Spectroscopy" @default.
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- W2083875490 doi "https://doi.org/10.1002/(sici)1099-0690(200005)2000:10<1953::aid-ejoc1953>3.0.co;2-q" @default.
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