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- W2083896137 abstract "Microcalorimetric measurements were made at elevated temperatures to determine the enthalpies of sublimation, thermal decomposition and bromination of [Re2(CO)10] and of [Re(CO)5X] (X CH3, Cl, Br), from which the standard enthalpies of formation ΔHof (c), ΔHof (g), were derived as follows (values in kJ mol−1): [Re2(CO)10] −(1660±11), −(1159±11); [Re(CO)5CH3] −(830±6), −(760±6); [Re(CO)5Cl] −(986±18), −(877±18); [Re(CO)5Br] −(950±8), −(858±8). The bond dissociation enthalpies D(X-Re(CO)5) are derived as 220 (X CH3), 314 (X Cl), 283 (X Br) kJ mol−1 relative to the value 187 kJ mol−1 for D(Re-Re) in [Re2(CO)10]." @default.
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- W2083896137 date "1983-12-01" @default.
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- W2083896137 title "Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives" @default.
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- W2083896137 doi "https://doi.org/10.1016/0022-328x(83)87182-4" @default.
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