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- W2083962035 abstract "The microwave spectra of 14N- and 15N-benzonitrile-argon have been recorded using a pulsed molecular beam Fourier transform microwave spectrometer. In the case of 14N-benzonitrile-argon, the rotational constants were determined to be A = 1347.7899(12) MHz, B = 1006.02030(94) MHz, C = 719.81749(24) MHz. The quartic centrifugal distortion constants (van Eijck) are D'J = 3.9982(14) kHz, D'JK = −15.3062(79) kHz, D'K = 21.8510(92) kHz, d'J = 1.65065(83) kHz, R'6 = 0.03043(38) kHz, and the 14N-nuclear quadrupole coupling constants are χaa = −0.4479(17) MHz, χbb-χcc = −4.1255(17) MHz. For 15N-benzonitrile-argon the rotational constants were found to be A = 1335.09150(30) MHz, B = 989.86421(15) MHz, and C = 707.91548(07) MHz. The centrifugal distortion constants are of the same magnitude as for the 14N-isotopomer. The argon atom is placed 3.545 Å above the center of the ring plane. In addition, the spectra of benzonitrile and six isotopic species have been reinvestigated; the derived constants and the resulting structure are of higher accuracy than in earlier work." @default.
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- W2083962035 date "1994-07-01" @default.
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- W2083962035 title "The rotational spectrum of the benzonitrile-argon van der Waals complex" @default.
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- W2083962035 doi "https://doi.org/10.1002/bbpc.19940980713" @default.
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