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• W2083969901 abstract "Femtosecond two-color pump–probe spectroscopy is used to measure the vibrational lifetime of the O–H stretch vibration in solutions of KF, NaCl, NaBr, and NaI in HDO:D2O. We observe a slow component (roughly 2–4 times slower than in HDO:D2O) in the decay of the absorption change, which is due to O–H groups that are hydrogen bonded to the dissolved anions. The time constant of this slow component depends on the nature of the anions and is observed to decrease with temperature, in contrast with the temperature dependence of the relaxation of the OH stretch vibration in pure HDO:D2O." @default.
• W2083969901 created "2016-06-24" @default.
• W2083969901 creator A5014152856 @default.
• W2083969901 creator A5050763048 @default.
• W2083969901 date "2003-03-01" @default.
• W2083969901 modified "2023-09-27" @default.
• W2083969901 title "Vibrational relaxation of liquid water in ionic solvation shells" @default.
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• W2083969901 doi "https://doi.org/10.1016/s0009-2614(03)00123-4" @default.
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