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• W2083977885 abstract "A study of the temperature dependence of the ultraviolet‐visible absorption cross sections for NO 2 has been made in the temperature range 213–298 K and between 310 and 570 nm using a diode array spectrometer. Analysis of the experimental data allowed the simultaneous measurement of the NO 2 and N 2 O 4 cross sections and the equilibrium constant for the dimerization of NO 2 . The absorption cross sections were measured at a spectral resolution of 0.54 nm full width at half maximum (FWHM) and are presented for use in the analysis of differential absorption spectra of atmospheric NO 2 . Averaged cross section data for NO 2 are presented for use in photolysis rate calculations. Values of cross sections for N 2 O 4 and equilibrium constant for the association of NO 2 are presented in the range 213 to 263 K. No temperature effect was observed on the overall shape of the NO 2 absorption spectrum or on the averaged cross section values used for calculating atmospheric photolysis rates. Changes in the fine structure of the NO 2 spectrum with temperature are observed and this has important implications for measurements of atmospheric NO 2 made by ultraviolet‐visible absorption techniques." @default.
• W2083977885 created "2016-06-24" @default.
• W2083977885 creator A5016963952 @default.
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• W2083977885 date "1994-11-20" @default.
• W2083977885 modified "2023-10-18" @default.
• W2083977885 title "Temperature dependent ultraviolet‐visible absorption cross sections of N₂O and N₂O₄: Low‐temperature measurements of the equilibrium constant for 2NO₂ ⇌ N₂O₄" @default.
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• W2083977885 doi "https://doi.org/10.1029/94jd01635" @default.
• W2083977885 hasPublicationYear "1994" @default.
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