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- W2083987041 abstract "The interactions were studied of metallocenes and their permethylated analogues of the iron subgroup (M = Fe, Ru, Os) with trifluoroacetic acid in low-polar media. IR and UV-Vis spectra, over a wide temperature range, proved that formation of the molecular hydrogen-bonded complex (OH ⋯ M) is the first stage of protonation. The ionic H-complexes of the M+H ⋯ O− type are formed as a result of proton transfer. The influences of the metal, the substituents on the Cp-ring and of the concentration of acid on this acid-base equilibrium are discussed." @default.
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- W2083987041 date "1994-02-01" @default.
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- W2083987041 title "Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup" @default.
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- W2083987041 doi "https://doi.org/10.1016/0022-328x(94)87063-2" @default.
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