Matches in SemOpenAlex for { <https://semopenalex.org/work/W2083993314> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2083993314 endingPage "160" @default.
- W2083993314 startingPage "154" @default.
- W2083993314 abstract "Oxidation of solid and liquid zinc by water (temperature 335–648 °C, pressure 13.7–31.2 MPa, water density 0.045–0.420 g/cm3), supercritical CO2 (514–600 °C, 7.1–24.4 MPa, 0.041–0.158 g/cm3), mixture of H2O/CO2 (140–600 °C, 30 MPa, water density 0.026–0.569 g/cm3, initial ratio of [H2O]0/[CO2]0 = 0.46–2.75 mol/mol) has been studied. In pure CO2, besides CO, carbons are formed and in mixtures H2O/CO2 along with H2 and CO, paraffin and aromatic hydrocarbons, alcohols and formaldehyde are synthesized. Combustible products composition depends on the temperature and ratio of [H2O]/[CO2] in the mixture. In every experiment ZnO nanoparticles formation was observed. Cluster mechanism of nanostructured ZnO generation has been proposed and kinetic parameters of this process have been revealed. Temperature dependence of the rate constant of Zn reacting with H2O is described by the equation kW(T) = 1.09 × 10−4 exp(−53.23 (kJ/mol)/RT). At the same temperature rate constant of Zn reacting with CO2 is 44 times less than kW, and the rate constant of Zn reacting with H2O/CO2 mixture is 25.4% less than kW." @default.
- W2083993314 created "2016-06-24" @default.
- W2083993314 creator A5000926560 @default.
- W2083993314 creator A5039161430 @default.
- W2083993314 creator A5045082537 @default.
- W2083993314 creator A5046312350 @default.
- W2083993314 date "2009-03-01" @default.
- W2083993314 modified "2023-09-23" @default.
- W2083993314 title "ZnO nanoparticles formation by reactions of bulk Zn with H2O and CO2 at sub- and supercritical conditions: I. Mechanism and kinetics of reactions" @default.
- W2083993314 cites W119445111 @default.
- W2083993314 cites W1972903329 @default.
- W2083993314 cites W1982235439 @default.
- W2083993314 cites W1990536516 @default.
- W2083993314 cites W2010545709 @default.
- W2083993314 cites W2021751853 @default.
- W2083993314 cites W2022144144 @default.
- W2083993314 cites W2027110794 @default.
- W2083993314 cites W2029204584 @default.
- W2083993314 cites W2031416526 @default.
- W2083993314 cites W2038485626 @default.
- W2083993314 cites W2038603505 @default.
- W2083993314 cites W2068768241 @default.
- W2083993314 cites W2085135515 @default.
- W2083993314 cites W2087277752 @default.
- W2083993314 cites W2099252199 @default.
- W2083993314 cites W2100684606 @default.
- W2083993314 cites W2120105133 @default.
- W2083993314 cites W55775875 @default.
- W2083993314 cites W1989369798 @default.
- W2083993314 doi "https://doi.org/10.1016/j.supflu.2008.11.004" @default.
- W2083993314 hasPublicationYear "2009" @default.
- W2083993314 type Work @default.
- W2083993314 sameAs 2083993314 @default.
- W2083993314 citedByCount "30" @default.
- W2083993314 countsByYear W20839933142012 @default.
- W2083993314 countsByYear W20839933142013 @default.
- W2083993314 countsByYear W20839933142014 @default.
- W2083993314 countsByYear W20839933142016 @default.
- W2083993314 countsByYear W20839933142017 @default.
- W2083993314 countsByYear W20839933142019 @default.
- W2083993314 countsByYear W20839933142020 @default.
- W2083993314 crossrefType "journal-article" @default.
- W2083993314 hasAuthorship W2083993314A5000926560 @default.
- W2083993314 hasAuthorship W2083993314A5039161430 @default.
- W2083993314 hasAuthorship W2083993314A5045082537 @default.
- W2083993314 hasAuthorship W2083993314A5046312350 @default.
- W2083993314 hasConcept C113196181 @default.
- W2083993314 hasConcept C118419359 @default.
- W2083993314 hasConcept C121332964 @default.
- W2083993314 hasConcept C127413603 @default.
- W2083993314 hasConcept C148898269 @default.
- W2083993314 hasConcept C155672457 @default.
- W2083993314 hasConcept C178790620 @default.
- W2083993314 hasConcept C185592680 @default.
- W2083993314 hasConcept C2775930285 @default.
- W2083993314 hasConcept C42360764 @default.
- W2083993314 hasConcept C535196362 @default.
- W2083993314 hasConcept C62520636 @default.
- W2083993314 hasConcept C93391505 @default.
- W2083993314 hasConceptScore W2083993314C113196181 @default.
- W2083993314 hasConceptScore W2083993314C118419359 @default.
- W2083993314 hasConceptScore W2083993314C121332964 @default.
- W2083993314 hasConceptScore W2083993314C127413603 @default.
- W2083993314 hasConceptScore W2083993314C148898269 @default.
- W2083993314 hasConceptScore W2083993314C155672457 @default.
- W2083993314 hasConceptScore W2083993314C178790620 @default.
- W2083993314 hasConceptScore W2083993314C185592680 @default.
- W2083993314 hasConceptScore W2083993314C2775930285 @default.
- W2083993314 hasConceptScore W2083993314C42360764 @default.
- W2083993314 hasConceptScore W2083993314C535196362 @default.
- W2083993314 hasConceptScore W2083993314C62520636 @default.
- W2083993314 hasConceptScore W2083993314C93391505 @default.
- W2083993314 hasIssue "2" @default.
- W2083993314 hasLocation W20839933141 @default.
- W2083993314 hasOpenAccess W2083993314 @default.
- W2083993314 hasPrimaryLocation W20839933141 @default.
- W2083993314 hasRelatedWork W1872501167 @default.
- W2083993314 hasRelatedWork W1986974960 @default.
- W2083993314 hasRelatedWork W2043757586 @default.
- W2083993314 hasRelatedWork W2105567124 @default.
- W2083993314 hasRelatedWork W2399973061 @default.
- W2083993314 hasRelatedWork W2406591841 @default.
- W2083993314 hasRelatedWork W2467156858 @default.
- W2083993314 hasRelatedWork W2748952813 @default.
- W2083993314 hasRelatedWork W2952763657 @default.
- W2083993314 hasRelatedWork W2952897012 @default.
- W2083993314 hasVolume "48" @default.
- W2083993314 isParatext "false" @default.
- W2083993314 isRetracted "false" @default.
- W2083993314 magId "2083993314" @default.
- W2083993314 workType "article" @default.