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- W2083997612 abstract "Die Pentaalkyle (CH3)5As und (CH3)5Sb reagieren mit äquivalenten Mengen einfacher Alkohole, Hydroxylamine und Oxime unter Methanabspaltung zu Produkten der Zusammensetzung (CH3)4MX (mit X = OR, ONH2, ONR2, ONCR2 und M = As, Sb). Die Schwingungs- und Tieftemperatur-1H-NMR-Spektren sprechen für eine trigonal-bipyramidale Struktur dieser monomeren Verbindungen. Monomeric Tetramethylarsenic and Antimony Compounds with Coordination Number Five at the Central Atom The pentaalkyl compounds (CH3)5As and (CH3)5Sb react with aequimolar amounts of alcohols, hydroxylamines, and oximes to produce methane and the compounds (CH3)4MX (with X = OR, ONH2, ONR2, ONCR2 and MAs, Sb). According to vibrational spectra and low temperature 1H-n.m.r. spectra the monomeric compounds posses a trigonal bipyramidal structure." @default.
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- W2083997612 date "1977-06-01" @default.
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- W2083997612 title "Monomere Tetramethylarsen- und Antimon-Verbindungen mit f�nffacher Koordination am Zentralatom" @default.
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- W2083997612 doi "https://doi.org/10.1002/zaac.19774310109" @default.
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