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- W2084030021 abstract "Abstract Crystals of PtCl 3 are obtained from the vapour phase in closed fused silica ampoules at temperatures near 785 K and at a chlorine pressure of about 26 atm. The thermodynamic parameters characterizing the single-phase field of solid PtCl 3 are determined. The growth of the crystals results from vapour transport which is a combination of a sublimation and two dissociative reactions. The complex transport is investigated using the solubility theory of Schafer. The theory reveals an increase in the transport rate with increasing chlorine pressure when the source is heated to the temperature which separates the fields of solid PtCl 2 and PtCl 3 ." @default.
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- W2084030021 date "1988-02-01" @default.
- W2084030021 modified "2023-09-25" @default.
- W2084030021 title "On the growth of PtCl3 crystals from the vapour phase" @default.
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- W2084030021 doi "https://doi.org/10.1016/0022-5088(88)90093-8" @default.
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