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- W2084064897 abstract "We conducted simultaneous high-pressure $(P)$ and high-temperature $(T)$ unit-cell volume $(V)$ measurements of ${text{H}}_{2}text{O}$ ice VII in an externally heated diamond anvil cell using in situ synchrotron x-ray diffraction technique with an angle-dispersive system. Isothermal unit-cell volume of ice VII was collected at $P=33--50text{ }text{GPa}$ with $T=873text{ }text{K}$. Nonisothermal experiments at $T=430--740text{ }text{K}$ and $P=19--37text{ }text{GPa}$ were also conducted to further constrain $Ptext{ensuremath{-}}Vtext{ensuremath{-}}T$ properties of ice VII. Using the existing 300 K compression data for an equation of state (EoS) at the reference temperature, a thermal EoS of ice VII was constructed from the collected high-$Ptext{ensuremath{-}}T$ data. The melting temperature of ice VII was computed up to $P=40text{ }text{GPa}$ by thermodynamic calculations with the newly constructed EoS of ice VII. The resulting melting temperatures are higher than that of previous calculations since the new EoS gives a smaller molar volume of ice VII. In contrast, the calculated melting curves are consistent with recent experimental estimates." @default.
- W2084064897 created "2016-06-24" @default.
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- W2084064897 date "2010-10-05" @default.
- W2084064897 modified "2023-09-30" @default.
- W2084064897 title "Simultaneous high-pressure and high-temperature volume measurements of ice VII and its thermal equation of state" @default.
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- W2084064897 doi "https://doi.org/10.1103/physrevb.82.134103" @default.
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