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- W2084089781 endingPage "615" @default.
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- W2084089781 abstract "Synthetic polymers present many unique separations challenges because, unlike small organic molecules, they consist of a distribution of structurally different chains. Each macromolecule can differ in chain length and end groups; stereochemical and structural isomers are possible along with unique branching architectures. Copolymers are further complicated by the combination of these potential variables with varying ratios and sequence distributions of their comonomer units. Liquid chromatography of individual synthetic polymers is limited by the solution properties of macromolecules to a narrow selection of solvents. In particular the thermodynamic considerations of polymer dissolution are strongly influenced by entropic factors. The application of reversed-phase liquid chromatography to the separation of synthetic polymers is characterized by the delicate balance between strong solvation interactions and weak adsorption interactions and is often further complicated by polymer solubility limitations in gradient elution separations." @default.
- W2084089781 created "2016-06-24" @default.
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- W2084089781 date "1993-12-01" @default.
- W2084089781 modified "2023-10-14" @default.
- W2084089781 title "Chemical composition separation of synthetic polymers by reversed-phase liquid chromatography" @default.
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- W2084089781 doi "https://doi.org/10.1016/0021-9673(93)80821-o" @default.
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