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- W2084098894 abstract "Abstract Highly selective transfer hydrogenolysis of CFC-113a (CF3CCl3) to HCFC-123 (CF3CHCl2) was accomplished in the presence of metal powder (Fe or Ni) in THF at 90°C under 8 atm of He. Pressure effects on the catalytic activities depend on the nature of metal catalysts and this behavior can be explained by a different rate determining step in each system. Activation of the C–H bond of THF on metal powder aided by η2 coordinated aldehydes is believed to occur first to produce electron-rich metal hydrides, which enhance the activation of the C–Cl bond of CFC-113a. Then reductive elimination follows to produce HCFC-123. This series of reactions was supported by experiments using deuterated THF and/or DMF and with p-substituted benzaldehydes." @default.
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- W2084098894 date "1999-02-01" @default.
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- W2084098894 title "Transfer hydrogenolysis of CFC-113a with aldehydes and metallic Fe or Ni" @default.
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