FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2084133020> ?p ?o ?g. }

• W2084133020 endingPage "376" @default.
• W2084133020 startingPage "365" @default.
• W2084133020 abstract "The geometric and electronic structure of NO bound to reduced protocatechuate 3,4-dioxygenase and its substrate (3,4-dihydroxybenzoate, PCA) complex have been examined by X-ray absorption (XAS), UV−vis absorption (Abs), magnetic circular dichroism (MCD), and variable temperature variable field (VTVH) MCD spectroscopies. The results are compared to those previously published on model complexes described as {FeNO}7 systems in which an S = 5/2 ferric center is antiferromagnetically coupled to an S = 1 NO-. XAS pre-edge analysis indicates that the Fe−NO units in FeIIIPCD{NO-} and FeIIIPCD{PCA,NO-} lack the greatly increased pre-edge intensity representative of most {FeNO}7 model sites. Furthermore, from extended X-ray absorption fine structure (EXAFS) analysis, the FeIIIPCD{NO-} and FeIIIPCD{PCA,NO-} active sites are shown to have an Fe−NO distance of at least 1.91 Å, ≈0.2 Å greater than those found in the model complexes. The weakened Fe−NO bond is consistent with the overall lengthening of the bond lengths and the fact that VTVH MCD data show that NO- → FeIII CT transitions are no longer polarized along the z-axis of the zero-field splitting tensor. The weaker Fe−NO bond derives from the strong donor interaction of the endogenous phenolate and substrate catecholate ligands, which is observed from the increased intensity in the CT region relative to that of {FeNO}7 model complexes, and from the shift in XAS edge position to lower energy. As NO is an analogue of O2, the effect of endogenous ligand donor strength on the Fe−NO bond has important implications with respect to O2 activation by non-heme iron enzymes." @default.
• W2084133020 created "2016-06-24" @default.
• W2084133020 creator A5014518485 @default.
• W2084133020 creator A5019917073 @default.
• W2084133020 creator A5024342453 @default.
• W2084133020 creator A5034459474 @default.
• W2084133020 creator A5045161756 @default.
• W2084133020 creator A5053214968 @default.
• W2084133020 creator A5069023264 @default.
• W2084133020 creator A5072260476 @default.
• W2084133020 creator A5084323096 @default.
• W2084133020 date "2002-12-17" @default.
• W2084133020 modified "2023-10-16" @default.
• W2084133020 title "Spectroscopic Studies of the Effect of Ligand Donor Strength on the Fe−NO Bond in Intradiol Dioxygenases" @default.
• W2084133020 cites W1195674231 @default.
• W2084133020 cites W1509366823 @default.
• W2084133020 cites W1551004756 @default.
• W2084133020 cites W1588380766 @default.
• W2084133020 cites W1628593931 @default.
• W2084133020 cites W1975180992 @default.
• W2084133020 cites W1981689753 @default.
• W2084133020 cites W1983848768 @default.
• W2084133020 cites W1988841674 @default.
• W2084133020 cites W1994373735 @default.
• W2084133020 cites W1994643435 @default.
• W2084133020 cites W1995485797 @default.
• W2084133020 cites W2006946556 @default.
• W2084133020 cites W2020399106 @default.
• W2084133020 cites W2021532248 @default.
• W2084133020 cites W2047636928 @default.
• W2084133020 cites W2048267273 @default.
• W2084133020 cites W2052895859 @default.
• W2084133020 cites W2053417509 @default.
• W2084133020 cites W2055239042 @default.
• W2084133020 cites W2062597634 @default.
• W2084133020 cites W2068254002 @default.
• W2084133020 cites W2073940365 @default.
• W2084133020 cites W2075857821 @default.
• W2084133020 cites W2077749836 @default.
• W2084133020 cites W2078171437 @default.
• W2084133020 cites W2093954547 @default.
• W2084133020 cites W2109073032 @default.
• W2084133020 cites W2120104062 @default.
• W2084133020 cites W2338151994 @default.
• W2084133020 cites W2952561138 @default.
• W2084133020 cites W3005058788 @default.
• W2084133020 doi "https://doi.org/10.1021/ic025906f" @default.
• W2084133020 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12693216" @default.
• W2084133020 hasPublicationYear "2002" @default.
• W2084133020 type Work @default.
• W2084133020 sameAs 2084133020 @default.
• W2084133020 citedByCount "26" @default.
• W2084133020 countsByYear W20841330202012 @default.
• W2084133020 countsByYear W20841330202013 @default.
• W2084133020 countsByYear W20841330202014 @default.
• W2084133020 countsByYear W20841330202015 @default.
• W2084133020 countsByYear W20841330202020 @default.
• W2084133020 crossrefType "journal-article" @default.
• W2084133020 hasAuthorship W2084133020A5014518485 @default.
• W2084133020 hasAuthorship W2084133020A5019917073 @default.
• W2084133020 hasAuthorship W2084133020A5024342453 @default.
• W2084133020 hasAuthorship W2084133020A5034459474 @default.
• W2084133020 hasAuthorship W2084133020A5045161756 @default.
• W2084133020 hasAuthorship W2084133020A5053214968 @default.
• W2084133020 hasAuthorship W2084133020A5069023264 @default.
• W2084133020 hasAuthorship W2084133020A5072260476 @default.
• W2084133020 hasAuthorship W2084133020A5084323096 @default.
• W2084133020 hasConcept C107861141 @default.
• W2084133020 hasConcept C110715899 @default.
• W2084133020 hasConcept C111368507 @default.
• W2084133020 hasConcept C11181451 @default.
• W2084133020 hasConcept C115624301 @default.
• W2084133020 hasConcept C116569031 @default.
• W2084133020 hasConcept C119824511 @default.
• W2084133020 hasConcept C121332964 @default.
• W2084133020 hasConcept C125287762 @default.
• W2084133020 hasConcept C127313418 @default.
• W2084133020 hasConcept C1276947 @default.
• W2084133020 hasConcept C133571119 @default.
• W2084133020 hasConcept C145148216 @default.
• W2084133020 hasConcept C147597530 @default.
• W2084133020 hasConcept C155860418 @default.
• W2084133020 hasConcept C170493617 @default.
• W2084133020 hasConcept C178790620 @default.
• W2084133020 hasConcept C185592680 @default.
• W2084133020 hasConcept C24890656 @default.
• W2084133020 hasConcept C2777289219 @default.
• W2084133020 hasConcept C32891209 @default.
• W2084133020 hasConcept C4839761 @default.
• W2084133020 hasConcept C55493867 @default.
• W2084133020 hasConcept C57805442 @default.
• W2084133020 hasConcept C62284982 @default.
• W2084133020 hasConcept C62520636 @default.
• W2084133020 hasConcept C68563686 @default.
• W2084133020 hasConcept C71240020 @default.
• W2084133020 hasConcept C8010536 @default.
• W2084133020 hasConcept C86025842 @default.
• W2084133020 hasConcept C99509065 @default.

• next