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- W2084153518 abstract "Processing operations such as milling, change the chemical structure of rubber. Infrared (IR) spectroscopy and electron spectroscopy for chemical analysis (ESCA) have been used to detect the formation of functional groups during the milling of natural rubber (NR), epoxidised natural rubber (ENR), styrene butadiene rubber (SBR), neoprene (CR), and acrylic rubber (AR). The concentration of carbonyl () groups as detected by IR spectroscopy increases with the time of milling for all the rubbers. The concentration of hydroxyl groups (OH) in NR and ENR also increases during milling. ESCA spectra of the rubbers before and after milling reveal that the peaks are broader for milled rubber, and that the concentration of oxygen is also greater. In the case of ENR, however, the concentration of epoxide rings decreases and that of furan rings increases with the time of milling." @default.
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- W2084153518 date "1992-06-25" @default.
- W2084153518 modified "2023-09-22" @default.
- W2084153518 title "Structural changes in rubber during milling" @default.
- W2084153518 doi "https://doi.org/10.1002/app.1992.070450601" @default.
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