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- W2084186250 abstract "A novel thioantimonate(III) [(CH3NH3)1.03K2.97]Sb12S20·1.34H2O was synthesized hydrothermally. It crystallizes in space groupP1, witha=11.9939(7) Å,b=12.8790(8) Å,c=14.9695(9) Å,α=100.033(1)°,β=99.691(1)°,γ=108.582(1)°,V=2095.3(2) Å3, andZ=2. The structure is determined from single crystal X-ray diffraction data collected at room temperature and refined toR(F)=0.037. In the crystal structure, each Sb(III) atoms has short bonds (2.37–2.58 Å) to three S atoms. The pyramidal [SbS3] groups share common S atoms forming two types of centrosymmetric [Sb12S20] rings with the same topology. These rings are interconnected by weaker Sb–S bonds (2.92–3.29 Å) into 2-dimensional layers. Adjacent layers are parallel with K+and CH3NH+3ions and H2O molecules located between them. Variation of bond valence sums calculated for the Sb(III) cations is found to be correlated with the coordination geometry. This is interpreted as due to the stereochemical activity of their lone electron pairs." @default.
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- W2084186250 date "1998-11-01" @default.
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- W2084186250 title "Hydrothermal Synthesis and Crystal Structure of [(CH3NH3)1.03K2.97]Sb12S20·1.34H2O" @default.
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- W2084186250 doi "https://doi.org/10.1006/jssc.1998.7905" @default.
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