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• W2084263750 abstract "Abstract Organically modified silicate (ormosil) materials doped with [4,4′-dimethyl-2,2′-bipyridine-bis(2,2′-bipyridine)] ruthenium(II) dichloride ([Ru-mbpy] 2+ ) and [4,4′-dimethylformate-2,2′-bipyridine-bis(2,2′-bipyridine)] ruthenium(II) dichloride ([Ru-dmfbpy] 2+ ) were prepared by a sol–gel procedure for oxygen-sensing applications. The results indicated that the concentrations of the Ru(II) diimine complexes obviously influenced the linearity of Stern–Volmer plots ( I 0  / I vs. O 2 %). The best suitable concentrations of [Ru-mbpy] 2+ and [Ru-dmfbpy] 2+ in the sol for oxygen sensors were found to be 1.0 × 10 − 3  M and 2.5 × 10 − 3  M, respectively. The fluorescence quenching time and recovery time of oxygen sensor doped with [Ru-mbpy] 2+ (1.0 × 10 − 3  M) were 18 s and 38 s and those doped with [Ru-dmfbpy] 2+ (1.0 × 10 − 3  M) were 13 s and 32 s, respectively. The oxygen sensor based on Ru(II) complex modified by esterification demonstrated excellent linear calibration relationship and improved long-term stability." @default.
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• W2084263750 date "2007-06-01" @default.
• W2084263750 modified "2023-09-25" @default.
• W2084263750 title "Oxygen-sensing properties of ormosil hybrid materials doped with ruthenium(II) complexes via a sol–gel process" @default.
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• W2084263750 doi "https://doi.org/10.1016/j.matlet.2006.11.106" @default.
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