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- W2084301116 abstract "Abstract Reduction of the (η 1 ,η 5 -R 2 NC 2 H 4 C 5 Me 4 )CoCl complexes (R=Me, R 2 =cyclo-C 4 H 8 ), prepared by treating CoCl 2 with 2-dimethylaminoethyl- or 2-pyrrolidinylethyl-tetramethylcyclopentadienyl-lithium, with active-Mg in the presence of ethylene or dienes leads to the formation of (η 5 -R 2 NC 2 H 4 C 5 Me 4 )(CH 2 :CH 2 ) 2 Co(I) or (η 5 -R 2 NC 2 H 4 C 5 Me 4 )(diene)Co(I) complexes. These react with ethereal HBF 4 with protonation of the amine followed, in the case of the diene complexes, by transfer of the proton to the diene to give (η 1 ,η 5 -R 2 NC 2 H 4 C 5 Me 4 )(η 3 -allyl)Co(III)-salts." @default.
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- W2084301116 date "2000-07-01" @default.
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- W2084301116 title "Amino-substituted cyclopentadienyl cobalt complexes" @default.
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- W2084301116 doi "https://doi.org/10.1016/s0022-328x(00)00244-8" @default.
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