FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2084313474> ?p ?o ?g. }

• W2084313474 endingPage "86" @default.
• W2084313474 startingPage "73" @default.
• W2084313474 abstract "Single-rate transport models are commonly used for interpreting sorption-related mass transfer in porous media, often with the intention of approximating the kinetics of the sorption process. Among the most commonly used single-rate models are the two-site first-order (TSFO) and the two-site radial diffusion (TSRD) models. We fitted the parameters of the TSFO and TSRD models to simulated breakthrough data of hypothetical column experiments in which sorption rates were described by a γ-distributed sorption sites (GS) model. Our objective was to determine the conditions under which the assumption of a single-rate sorption parameter will be applicable to systems with heterogeneous sorption rates. We were further interested in knowing in what manner the fitted single-rate nonequilibrium model parameters depend upon the conditions under which the data were obtained. The considered hypothetical cases covered a range of experimental conditions and involved compounds with different sorption characteristics. The study revealed that the goodness of fit of the single rate models in simulating the transport of solutes exhibiting heterogeneous sorption rates is affected by solute residence time and pulse injection duration. Compared to the TSFO model, the TSRD model generally results in better prediction of solute transport affected by heterogeneous sorption kinetics. In addition, for such systems, the nonequilibrium parameters fitted using the TSFO model and their counterparts in the TSRD model are highly correlated. Moreover, an increase in the fitted mass transfer timescale of each of the single-rate models is coupled with an increase in the associated fraction of instantaneous sorption sites. A strong correlation was found between the time of the experiment and the product of the fitted characteristic time for mass transfer, pulse duration, and solute residence time. The correlation explains many of the variations in the mass transfer timescale encountered when single-rate sorption approaches were utilized to model solute transport in previous miscible displacement studies." @default.
• W2084313474 created "2016-06-24" @default.
• W2084313474 creator A5006688034 @default.
• W2084313474 creator A5018132333 @default.
• W2084313474 date "2014-02-01" @default.
• W2084313474 modified "2023-10-18" @default.
• W2084313474 title "Modeling solute transport affected by heterogeneous sorption kinetics using single-rate nonequilibrium approaches" @default.
• W2084313474 cites W1544651089 @default.
• W2084313474 cites W1573171955 @default.
• W2084313474 cites W1632977450 @default.
• W2084313474 cites W1653420972 @default.
• W2084313474 cites W1659987100 @default.
• W2084313474 cites W1864410639 @default.
• W2084313474 cites W1964152726 @default.
• W2084313474 cites W1964195699 @default.
• W2084313474 cites W1965504478 @default.
• W2084313474 cites W1967892294 @default.
• W2084313474 cites W1972218439 @default.
• W2084313474 cites W1976164911 @default.
• W2084313474 cites W1976768522 @default.
• W2084313474 cites W1979948828 @default.
• W2084313474 cites W1983552844 @default.
• W2084313474 cites W1985327207 @default.
• W2084313474 cites W1985436822 @default.
• W2084313474 cites W1987315257 @default.
• W2084313474 cites W1992295222 @default.
• W2084313474 cites W1993440473 @default.
• W2084313474 cites W1994137489 @default.
• W2084313474 cites W1994255621 @default.
• W2084313474 cites W1995383786 @default.
• W2084313474 cites W1996191138 @default.
• W2084313474 cites W1997385547 @default.
• W2084313474 cites W2004320179 @default.
• W2084313474 cites W2004529940 @default.
• W2084313474 cites W2005078677 @default.
• W2084313474 cites W2007088370 @default.
• W2084313474 cites W2011582078 @default.
• W2084313474 cites W2013916472 @default.
• W2084313474 cites W2015187960 @default.
• W2084313474 cites W2016194783 @default.
• W2084313474 cites W2017183855 @default.
• W2084313474 cites W2020717411 @default.
• W2084313474 cites W2020767250 @default.
• W2084313474 cites W2023162344 @default.
• W2084313474 cites W2023558112 @default.
• W2084313474 cites W2023818956 @default.
• W2084313474 cites W2031471466 @default.
• W2084313474 cites W2031593283 @default.
• W2084313474 cites W2043341503 @default.
• W2084313474 cites W2043922553 @default.
• W2084313474 cites W2044235296 @default.
• W2084313474 cites W2046088791 @default.
• W2084313474 cites W2046227415 @default.
• W2084313474 cites W2047374306 @default.
• W2084313474 cites W2048904659 @default.
• W2084313474 cites W2057104134 @default.
• W2084313474 cites W2058428517 @default.
• W2084313474 cites W2062256070 @default.
• W2084313474 cites W2064079821 @default.
• W2084313474 cites W2064315697 @default.
• W2084313474 cites W2066109724 @default.
• W2084313474 cites W2067499973 @default.
• W2084313474 cites W2067968370 @default.
• W2084313474 cites W2068437576 @default.
• W2084313474 cites W2068872050 @default.
• W2084313474 cites W2069032765 @default.
• W2084313474 cites W2071473808 @default.
• W2084313474 cites W2075645075 @default.
• W2084313474 cites W2081142887 @default.
• W2084313474 cites W2082893249 @default.
• W2084313474 cites W2083328994 @default.
• W2084313474 cites W2084062752 @default.
• W2084313474 cites W2089671702 @default.
• W2084313474 cites W2091415871 @default.
• W2084313474 cites W2099111135 @default.
• W2084313474 cites W2100732378 @default.
• W2084313474 cites W2103296601 @default.
• W2084313474 cites W2107596731 @default.
• W2084313474 cites W2125418826 @default.
• W2084313474 cites W2127807490 @default.
• W2084313474 cites W2128899604 @default.
• W2084313474 cites W2135933888 @default.
• W2084313474 cites W2136750680 @default.
• W2084313474 cites W2143799591 @default.
• W2084313474 cites W2147982579 @default.
• W2084313474 cites W2153532948 @default.
• W2084313474 cites W2155723969 @default.
• W2084313474 cites W2164780482 @default.
• W2084313474 cites W4230189904 @default.
• W2084313474 cites W4244229228 @default.
• W2084313474 doi "https://doi.org/10.1016/j.jconhyd.2013.11.005" @default.
• W2084313474 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24365395" @default.
• W2084313474 hasPublicationYear "2014" @default.
• W2084313474 type Work @default.
• W2084313474 sameAs 2084313474 @default.
• W2084313474 citedByCount "12" @default.
• W2084313474 countsByYear W20843134742014 @default.
• W2084313474 countsByYear W20843134742015 @default.

• next