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- W2084340469 abstract "Water isotherms were obtained on cleaved NaCl crystals which had been treated with water vapor, HCl-H2O vapor and CO2-H2O vapor. These treatments are known to produce surfaces containing hydroxide, chloride and bicarbonate. The water isotherms were in accord with proposed structures for hydrogen-bonded first-layer adsorption of one molecule of H2O for each OH− site and one molecule of H2O for two Cl− sites or two HCO3− sites. The adsorption of krypton reflected only the surface area changes produced by crystallite growth resulting from surface dissolution in the adsorbed water layer and subsequent recrystallization during outgassing. Vacuum heating of NaCl powder at 180°C and 250°C after exposure to water vapor gave evidence of the conversion of the hydroxide surface to chloride surface by bulk diffusion." @default.
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- W2084340469 date "1968-09-01" @default.
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- W2084340469 title "Adsorption of water on sodium chloride: The effect of prior exposure to hydrogen chloride, carbon dioxide and water vapor" @default.
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- W2084340469 doi "https://doi.org/10.1016/0039-6028(68)90005-8" @default.
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