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- W2084351631 abstract "Infrared and Raman spectra are reported for liquid and solid C5H5BeCl, C5H5BeBH4, and C5H5BeBD4 and vibrational assignments of most of the C5H5, BeX, and skeletal modes are made. Conclusive evidence for a double hydrogen bridge configuration is found for C5H5BeBH4 and, in contrast to Be(BH4)2, this structure is unchanged in going from gas to liquid to solid. The C5H5 frequencies are in close accord with those of (C5H5)2Fe while the vibrations of the BeBH4 group are analogous to those reported earlier for the +BeBH4 ion in solid Be(BH4)2. Observation of several transitions for the skeletal torsional motion of C5H5BeBH4 implies that free internal rotation about the symmetry axis does not occur and calculations yield a value of 500 cm−1 for the tenfold torsional barrier. Raman polarization data are consistent with a low energy orientation which places the BeH2bB bridging plane and a Cs molecular symmetry plane in coincidence." @default.
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- W2084351631 date "1975-12-01" @default.
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- W2084351631 title "Vibrational spectra and torsional barrier of cyclopentadienyl beryllium borohydride, C5H5BeBH4" @default.
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