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- W2084367823 abstract "Abstract The ring-opening reactions of meso-epoxides with aniline and indole derivatives proceeded smoothly in water in the presence of Zn(II) and Cu(II) surfactant-type catalysts to afford the corresponding products in moderate to high yields with good to excellent enantioselectivities. Opposite enantiomers were obtained by using Sc(III) and Zn(II) or Cu(II) with the same chiral ligand. Crystal structures of these catalysts may explain the reversal of the enantioselectivity. Some reactions were also tested in dichloromethane (DCM), and it was revealed that the reactions proceeded faster in water than in DCM. Finally, several non-linear effect experiments suggested unique structure of these chiral catalysts." @default.
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- W2084367823 date "2010-06-15" @default.
- W2084367823 modified "2023-10-17" @default.
- W2084367823 title "ChemInform Abstract: Chiral Zinc(II) and Copper(II)-Catalyzed Asymmetric Ring-Opening Reactions of meso-Epoxides with Aniline and Indole Derivatives." @default.
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- W2084367823 doi "https://doi.org/10.1002/chin.201024064" @default.
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