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• W2084367974 endingPage "469" @default.
• W2084367974 startingPage "461" @default.
• W2084367974 abstract "Brief summaries are given of work on the vibrational spectra of the following compounds. (1) N(SiH 3 ) 3 . A Raman study of the 14 N −15 N isotopic shift of the totally symmetric NSi 3 stretching mode confirms that the heavy atom skeleton is planar in the gas phase. In condensed phases it is slightly distorted from D 3h in some undetermined manner. (2) Si(NCO) 4 , Ge(NCO) 4 , and Ge(Na) 4 . Each of these molecules has some Raman bands with depolarization ratios between 0 and 0.75, showing that the molecules are not tetrahedral. (3) Cyclopropenone-d 0 and -d 2 . A good assignment of the fundamentals has been made, and the forms of the normal modes calculated. The bands at 1483 cm −1 (d 0 ) and 1409 cm −1 (d 2 ) are nearly pure =C stretches, making them the lowest such modes known. (4, 5) Tetramethylenecyclobutane and its perchloro derivative. The former is planar (D 4h ); the latter is not. (6) F 2 C=C=C=CF 2 . This is planar (D 2d ). (7) B 4 Cl 4 . This has an unusual B 4 tetrahedral cage. A reliable set of assignments has been made and force constants determined. (8) Trithiadiborolanes. The B 2 S 3 ring is planar." @default.
• W2084367974 created "2016-06-24" @default.
• W2084367974 creator A5051792728 @default.
• W2084367974 date "1975-11-01" @default.
• W2084367974 modified "2023-10-10" @default.
• W2084367974 title "Molecules We Have Recently Met" @default.
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• W2084367974 doi "https://doi.org/10.1366/000370275774455545" @default.
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