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• W2084391394 endingPage "155" @default.
• W2084391394 startingPage "148" @default.
• W2084391394 abstract "The asymmetric hydroformylation of styrene catalysed by rhodium complexes modified by monodentate phosphepine ligands has been investigated. The effects of a systematic variation of the phosphorus substituent on catalytic activity and selectivity are reported as well as the outcome of a combinatorial approach for the formation of mixed ligands complexes with several commercially available ligands. Effective catalytic systems have been devised for the reaction that provide for full conversion within 24 h and regioselectivity up to 96% in the branched aldehyde and enantioselectivities up to 48%. The use of bidentate ligands built up by binaphthyl-supported seven-membered phosphacyclic units does not allow for further improvement in the reaction outcome." @default.
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• W2084391394 date "2008-02-01" @default.
• W2084391394 modified "2023-10-09" @default.
• W2084391394 title "Novel rhodium catalyst for asymmetric hydroformylation of styrene: Study of electronic and steric effects of phosphorus seven-membered ring ligands" @default.
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• W2084391394 doi "https://doi.org/10.1016/j.molcata.2007.10.023" @default.
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