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• W2084405392 abstract "We have demonstrated that the combined use of enyne metathesis and metallotropic [1,3]-shift of the corresponding alkynyl ruthenium carbenes is a powerful synthetic tool to construct oligoenynes. In this reaction, alkynyl carbene intermediates formed from an initial ring-closing metathesis reaction (RCM) undergo repetitive [1,3]-shifts and RCMs to give the final products. Linear poly-1,3-diynes containing repeating functionality of the type −[XCH2CCCCCH2]n− generated long-chain conjugated oligoenynes up to n = 5." @default.
• W2084405392 created "2016-06-24" @default.
• W2084405392 creator A5047693100 @default.
• W2084405392 creator A5091250848 @default.
• W2084405392 date "2005-12-01" @default.
• W2084405392 modified "2023-09-26" @default.
• W2084405392 title "Metathesis and Metallotropy: A Versatile Combination for the Synthesis of Oligoenynes" @default.
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• W2084405392 doi "https://doi.org/10.1021/ja057153c" @default.
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