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- W2084409885 abstract "The complexes, [Co(L-val)(NH3)(tacn)]2+ (tacn=1,4,7-triazacyclononane), [Co(gly)(NH3)(Me-tacn)]2+ (Me-tacn=(2R)-2-methyl-1,4,7-triazacyclononane) have been prepared and separated into diastereomers by column chromatography. Six other complexes, [Co(a)(β-ala)(tacn)]n+ (a=CN−, NO2−, or NH3) and [Co(a)(gly)(tacdd)]n+ (a=NO2−, NCS−, or H2O; tacdd=1,5,9-triazacyclododecane) have also been prepared and resolved into enantiomers. By comparing the CD spectra of the L-valinato and the Me-tacn complexes with that of [Co(gly)(NH3)(tacn)]2+, the optical activities of [Co(a)(gly)(tacn)]+ are considered to be mainly derived from chiral arrangements of four kinds of donor atoms. The change from five-membered chelate ring to a six-membered one has slight influence upon the CD spectral shapes in the β-alaninato complex, but a large influence in the tacdd complexes." @default.
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- W2084409885 date "1982-07-01" @default.
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- W2084409885 title "Circular Dichroism Spectra of<i>fac(D)</i>-[Co(a)(BC)(DDD)<sup><i>n</i>+</sup>Type Complexes with 1,4,7-Triazacyclononane, (2<i>R</i>)-2-Methyl-1,4,7-triazacyclononane, and 1,5,9-Triazacyclododecane" @default.
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- W2084409885 doi "https://doi.org/10.1246/bcsj.55.2101" @default.
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