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- W2084424511 abstract "Abstract Syntheses of long-chain hydroxy-, methoxyalkylsilanes of the type (RSi(CH 3 ) 2 OH, R m SiY 4− m with R=C 12 H 25 , C 18 H 37 and Y=OH, OMe, m =1, 2, 3) ( 5 , 6 , 7a–c , 8a–c , 9a–c , 10a–c ) and alkylsilyl glycopyranosides ( 13 , 14 , 15a–c , 16a–c ) are reported. Hydroxyalkylsilanes ( 5 , 6 , 7a–c , 8a–c ) were prepared by the hydrolysis of alkylchlorosilanes ( 1a–c , 2a–c , 3 , 4 ) with NaHCO 3 –H 2 O in diethyl ether. Alkylchlorosilanes 1a–c and 2a–c react with KOMe in n -hexane to give methoxyalkylsilanes 9a–c and 10a–c , respectively. Alkylchlorosilanes 1a–c , 2a–c , 3 and 4 react direct with 2,3,4,6-tetra- O -acetyl-α/β- d -glucopyranose 12 in CH 2 Cl 2 to give alkylsilyl glucopyranosides 13 , 14 , 15a–c and 16a–c , respectively." @default.
- W2084424511 created "2016-06-24" @default.
- W2084424511 creator A5067929548 @default.
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- W2084424511 date "1999-10-01" @default.
- W2084424511 modified "2023-09-27" @default.
- W2084424511 title "Synthese und Charakterisierung von langkettigen siliciumhaltigen Hydroxy- und Methoxyverbindungen und Glucopyranosiden" @default.
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- W2084424511 doi "https://doi.org/10.1016/s0008-6215(99)00173-1" @default.
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