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• W2084461567 abstract "Quantum chemical calculations as well as vis absorption and fluorescence measurements of the pyridinium-N-phenolate betaine dye B30, dissolved in 1-chlorobutane at temperatures between 343 and 77 K, shed more light on the solvatochromism, thermosolvatochromism, and photophysical behavior of this probe dye, formerly used to establish an empirical scale of solvent polarity, called E(T)(30) or E(T)(N) scale. A new calculated gas-phase E(T)(30) value is reported. Complementary to recent work of Kharlanov and Rettig (J. Phys. Chem. A 2009, 113, 10693-10703), it is shown that fluorescence of B30 in 1-chlorobutane solution is observable already at temperatures just below the solvent's melting point and not only at 77 K. Analogous to increasing solvent polarity, decreasing solvent temperature leads to a large hypsochromic shift of the vis absorption band of B30, dissolved in 1-chlorobutane (Deltalambda = -245 nm from 797 nm at 343 K to 552 nm at 77 K). This thermosolvatochromism can be easily seen: the solution color changes from greenish yellow (343 K) to magenta-violet (77 K)." @default.
• W2084461567 created "2016-06-24" @default.
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• W2084461567 date "2010-05-06" @default.
• W2084461567 modified "2023-10-16" @default.
• W2084461567 title "On the Molecular Structure and UV/vis Spectroscopic Properties of the Solvatochromic and Thermochromic Pyridinium-<i>N</i>-Phenolate Betaine Dye B30" @default.
• W2084461567 cites W1541501717 @default.
• W2084461567 cites W1964471837 @default.
• W2084461567 cites W1966784353 @default.
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• W2084461567 cites W1972377723 @default.
• W2084461567 cites W1972383310 @default.
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• W2084461567 doi "https://doi.org/10.1021/jp1009302" @default.
• W2084461567 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20446695" @default.
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