FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2084492616> ?p ?o ?g. }

• W2084492616 endingPage "5160" @default.
• W2084492616 startingPage "5148" @default.
• W2084492616 abstract "We propose a new definition of excess adsorption for use in molecular models of adsorption. This definition implies the calibration of theoretical models in a manner mimicking the experimental calibration procedure. The method of theoretical calibration is developed on the example of helium calibration. The notions of the He calibrated pore volume and the He calibrated pore size are introduced, and the He calibrated theoretical excess isotherms are defined. The proposed method diminishes the discrepancies between the theoretical and the experimental excess adsorption isotherms and makes the theory and the experiment entirely consistent. The quantitative estimates are made by means of the nonlocal density functional theory (NLDFT) applied to the adsorption of He, N2, and CH4 in micropores of active carbons at liquid nitrogen and ambient temperatures. It is shown that the experimental He calibration affects significantly the excess isotherms of vapors and supercritical fluids in microporous carbons. The nonmonotonous excess isotherms in molecular size pores are predicted. The theoretical predictions of He adsorption are in qualitative agreement with the experimental isotherm measured on the BPL active carbon at 77 K. The theoretical calibration is recommended for adjustment of any molecular model of adsorption phenomena, such as density functional theory, molecular dynamics, and grand canonical and other Monte Carlo simulations." @default.
• W2084492616 created "2016-06-24" @default.
• W2084492616 creator A5013313042 @default.
• W2084492616 creator A5068732439 @default.
• W2084492616 date "1997-09-01" @default.
• W2084492616 modified "2023-10-02" @default.
• W2084492616 title "Calibration of Pore Volume in Adsorption Experiments and Theoretical Models" @default.
• W2084492616 cites W135807259 @default.
• W2084492616 cites W1845618662 @default.
• W2084492616 cites W1862976591 @default.
• W2084492616 cites W1979433627 @default.
• W2084492616 cites W1980704616 @default.
• W2084492616 cites W1987632561 @default.
• W2084492616 cites W1990070176 @default.
• W2084492616 cites W2005416456 @default.
• W2084492616 cites W2017785604 @default.
• W2084492616 cites W2021374437 @default.
• W2084492616 cites W2024108554 @default.
• W2084492616 cites W2029184831 @default.
• W2084492616 cites W2031594194 @default.
• W2084492616 cites W2047404361 @default.
• W2084492616 cites W2053011272 @default.
• W2084492616 cites W2062762813 @default.
• W2084492616 cites W2064853265 @default.
• W2084492616 cites W2066084871 @default.
• W2084492616 cites W2078241327 @default.
• W2084492616 cites W2079202142 @default.
• W2084492616 cites W2079579712 @default.
• W2084492616 cites W2083990481 @default.
• W2084492616 cites W2084041890 @default.
• W2084492616 cites W2090708545 @default.
• W2084492616 cites W2093937936 @default.
• W2084492616 cites W2096931488 @default.
• W2084492616 cites W2101146408 @default.
• W2084492616 cites W2158584131 @default.
• W2084492616 cites W2299270066 @default.
• W2084492616 cites W2318484608 @default.
• W2084492616 cites W2328106122 @default.
• W2084492616 cites W2331059300 @default.
• W2084492616 cites W4211184409 @default.
• W2084492616 cites W4243000817 @default.
• W2084492616 doi "https://doi.org/10.1021/la970266s" @default.
• W2084492616 hasPublicationYear "1997" @default.
• W2084492616 type Work @default.
• W2084492616 sameAs 2084492616 @default.
• W2084492616 citedByCount "153" @default.
• W2084492616 countsByYear W20844926162012 @default.
• W2084492616 countsByYear W20844926162013 @default.
• W2084492616 countsByYear W20844926162014 @default.
• W2084492616 countsByYear W20844926162015 @default.
• W2084492616 countsByYear W20844926162016 @default.
• W2084492616 countsByYear W20844926162017 @default.
• W2084492616 countsByYear W20844926162018 @default.
• W2084492616 countsByYear W20844926162019 @default.
• W2084492616 countsByYear W20844926162020 @default.
• W2084492616 countsByYear W20844926162021 @default.
• W2084492616 countsByYear W20844926162022 @default.
• W2084492616 countsByYear W20844926162023 @default.
• W2084492616 crossrefType "journal-article" @default.
• W2084492616 hasAuthorship W2084492616A5013313042 @default.
• W2084492616 hasAuthorship W2084492616A5068732439 @default.
• W2084492616 hasConcept C105795698 @default.
• W2084492616 hasConcept C118419359 @default.
• W2084492616 hasConcept C121332964 @default.
• W2084492616 hasConcept C147789679 @default.
• W2084492616 hasConcept C150394285 @default.
• W2084492616 hasConcept C165838908 @default.
• W2084492616 hasConcept C178790620 @default.
• W2084492616 hasConcept C185592680 @default.
• W2084492616 hasConcept C19499675 @default.
• W2084492616 hasConcept C20556612 @default.
• W2084492616 hasConcept C33923547 @default.
• W2084492616 hasConcept C546029482 @default.
• W2084492616 hasConcept C62520636 @default.
• W2084492616 hasConcept C86381522 @default.
• W2084492616 hasConcept C97355855 @default.
• W2084492616 hasConceptScore W2084492616C105795698 @default.
• W2084492616 hasConceptScore W2084492616C118419359 @default.
• W2084492616 hasConceptScore W2084492616C121332964 @default.
• W2084492616 hasConceptScore W2084492616C147789679 @default.
• W2084492616 hasConceptScore W2084492616C150394285 @default.
• W2084492616 hasConceptScore W2084492616C165838908 @default.
• W2084492616 hasConceptScore W2084492616C178790620 @default.
• W2084492616 hasConceptScore W2084492616C185592680 @default.
• W2084492616 hasConceptScore W2084492616C19499675 @default.
• W2084492616 hasConceptScore W2084492616C20556612 @default.
• W2084492616 hasConceptScore W2084492616C33923547 @default.
• W2084492616 hasConceptScore W2084492616C546029482 @default.
• W2084492616 hasConceptScore W2084492616C62520636 @default.
• W2084492616 hasConceptScore W2084492616C86381522 @default.
• W2084492616 hasConceptScore W2084492616C97355855 @default.
• W2084492616 hasIssue "19" @default.
• W2084492616 hasLocation W20844926161 @default.
• W2084492616 hasOpenAccess W2084492616 @default.
• W2084492616 hasPrimaryLocation W20844926161 @default.
• W2084492616 hasRelatedWork W1974396881 @default.
• W2084492616 hasRelatedWork W2026161195 @default.
• W2084492616 hasRelatedWork W2032042223 @default.

• next