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• W2084493763 startingPage "2517" @default.
• W2084493763 abstract "Conformers of 4-coordinate adducts of carbonyl compounds and diaza-, oxaza- and dioxaluminolidines were investigated by means of ab initio MO methods (RHF). Formaldehyde was used as a model of carbonyl compounds. Relative stabilities of the conformers indicate formation of syn adducts of carbonyl compounds and aluminolidines (CCO and aluminolidine ring syn about the AlOCO bond) to be favoured over that of the corresponding anti ones (all syn/anti ratios higher than 99:1, 6–31G//6–31G). The energetic preference for the formation of syn adducts of oxazaaluminolidines was about twice as high as that of diaza- or dioxaluminolidines of which the syn/anti selectivities were found to be practically equal." @default.
• W2084493763 created "2016-06-24" @default.
• W2084493763 creator A5069125847 @default.
• W2084493763 date "1993-01-01" @default.
• W2084493763 modified "2023-09-24" @default.
• W2084493763 title "Quantum chemical modeling of chiral catalysis. Part 14. On the coordination of carbonyl compounds to diaza-, oxaza- and dioxaluminolidines of potential use as chiral controllers in organic synthetic chemistry" @default.
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• W2084493763 doi "https://doi.org/10.1016/s0957-4166(00)82232-6" @default.
• W2084493763 hasPublicationYear "1993" @default.
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