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- W2084536005 abstract "The rearrangement of allylic sulphinates to sulphones is facilitated by palladium catalysis, treatment of the chiral trans-and cis-allyl sulphinates (S)-(–)-(1a)-(1c), and -(1e), and(S)-(–)-(1b)and -(1d)with a catalytic amount of the palladium catalysts (3)and(5)providing the corresponding chiral allyl sulphones,(S)-(+)-and(R)-(–)-(2a–c), respectively, in good yields; exceptionally the palladium catalysis of the rearrangement of (S)-(–)-(1f)produced (S)-(+)-(2c)." @default.
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- W2084536005 date "1984-01-01" @default.
- W2084536005 modified "2023-09-24" @default.
- W2084536005 title "Palladium-catalysed allylic sulphinate–sulphone rearrangements; asymmetric induction in the palladium-catalysed transfer of chiral sulphinates to sulphones" @default.
- W2084536005 doi "https://doi.org/10.1039/c39840000303" @default.
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