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- W2084540282 abstract "The slow combustion of ethane was experimentally studied by W. A. Bone and W. E. Stockings more than 25 years ago, and shown to proceed in successive stages of hydroxylation, thus :─ Interest in the subject has recently been revived, chiefly because of the conception of “ chain reactions, “ which (to quote a leading exponent) “ are now generally supposed to occur whenever many molecules are transformed per quantum in a photochemical change, “ and of the supposition that “ in the combustion of hydrocarbons bodies of a peroxide character are formed and that these act as a centres from which chains are propagated.” The mechanism of hydrocarbon combustion was fully discussed in Chapters XXVIII to XXX (pp. 354 to 400) of Bone and Townend’s “Flame and Combustion in Gases “ (1927), especially in relation to H. L. Callendar’s conclusion (from experiments on hexane and higher hydrocarbons) that the initial stage involves the formation of an alkyl peroxide (rather than of an alcohol) “ by the direct incorporation of the oxygen molecules in the hydrocarbon molecule and after direct collision, “ such peroxide subsequently giving rise to aldehydes and water as decomposition products. It was shown that while the two views are not as decomposition products. It was shown that while the two views are not mutually exclusive, and many perhaps even be supplementary, “ hydroxylation “ explains most of the known facts better than “ peroxidation. “ This conclusion was strenghtened by the results of Dr. D. T. A. Townend’s experiments on the partial combustion of methane at high initial pressures which, while quite understandable from the point of view of “ hydroxylation, ” seem incompatible with the idea of a primary peroxide formation. Also, it may be mentioned that in 1928 M. Stanislas Landa, in describing the results of his experimental study of the slow combustion of higher paraffins at 280 to 300°C., reported having isolated alcohols as well as aldehydes from the products in accordance with the “ hydroxylation ” theory." @default.
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- W2084540282 date "1930-11-03" @default.
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- W2084540282 title "The slow combustion of ethane" @default.
- W2084540282 doi "https://doi.org/10.1098/rspa.1930.0166" @default.
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