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• W2084553095 abstract "We study the electronic structure of three-dimensional nanoporous $mathrm{Ce}{mathrm{O}}_{2ensuremath{-}x}$ monoliths (aerogels) by soft x-ray absorption near-edge structure (XANES) spectroscopy. Atomic multiplet calculations are used to interpret high-resolution $mathrm{Ce}phantom{rule{0.2em}{0ex}}{M}_{4,5}$- and ${N}_{4,5}$-edge XANES spectra. Results show that aerogels with thicker ligaments, but with the same average size of crystallites, exhibit larger ${mathrm{Ce}}^{3+}$ content and, hence, higher oxygen deficiency." @default.
• W2084553095 created "2016-06-24" @default.
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• W2084553095 date "2007-12-19" @default.
• W2084553095 modified "2023-09-27" @default.
• W2084553095 title "Electronic structure of nanoporous ceria from x-ray absorption spectroscopy and atomic multiplet calculations" @default.
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• W2084553095 doi "https://doi.org/10.1103/physrevb.76.235420" @default.
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