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• W2084553441 abstract "Phase equilibria in the PrBaCuO system under varied oxygen partial pressure (pO2) is investigated. Stoichiometric PrBa2Cu3O7−δ (Pr123) does not exist for pO2 < 1 bar O2. Instead, nominal Pr123 is a mixture of Pr1+xBa2−xCu3O7+δ solid-solution (Pr123ss) and BaCuO2. When nominal Pr123 is processed at 900°C in 1 bar O2, the lower limit for x is 0.04. As the pO2 is lowered, the occupancy of the Pr ions on the Ba sites is decreased. The minimum lower limit of x is ∼ 0.01 at 900°C using a pO2 of 0.001 atm. Further reducing the pO2 causes the BaCu2O2 and PrBaO3 phases to form." @default.
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• W2084553441 date "1996-03-01" @default.
• W2084553441 modified "2023-09-29" @default.
• W2084553441 title "Phase equilibria in the PrBaCuO system under varied oxygen partial pressures" @default.
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• W2084553441 doi "https://doi.org/10.1016/0921-4534(96)00006-8" @default.
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