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- W2084555382 abstract "N-Heterocyclic carbenes can catalyze β-alkylations of a range of α,β-unsaturated esters, amides, and nitriles that bear pendant leaving groups to form a variety of ring sizes. In this process, the nucleophilic catalyst transiently transforms the normally electrophilic β carbon into a nucleophilic site through an unanticipated addition−tautomerization sequence." @default.
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- W2084555382 date "2006-01-17" @default.
- W2084555382 modified "2023-10-12" @default.
- W2084555382 title "Umpolung of Michael Acceptors Catalyzed by <i>N</i>-Heterocyclic Carbenes" @default.
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- W2084555382 doi "https://doi.org/10.1021/ja058222q" @default.
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