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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2084555720> ?p ?o ?g. }

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• W2084555720 abstract "Sequence control in chain-growth polymerization is still one of the most challenging topics in synthetic polymer chemistry in contrast to natural macromolecules with completely sequence-regulated structures like proteins and DNA. Here, we report the quantitative and highly selective 1:2 sequence-regulated radical copolymerization of naturally occurring (+)-d-limonene (L) and a maleimide (M) in fluoroalcohol giving chiral copolymers with high glass transition temperatures (220-250 degrees C) originating from the specific rigid cyclic structures of the monomers. Furthermore, the combination with a reversible addition-fragmentation chain transfer (RAFT) agent (C-S) via the controlled/living radical polymerization resulted in end-to-end sequence-regulated copolymers [C-(M-M-L)(n)-M-S] with both highly sequenced chain ends and main-chain repeating units as well as controlled molecular weights." @default.
• W2084555720 created "2016-06-24" @default.
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• W2084555720 date "2010-06-30" @default.
• W2084555720 modified "2023-10-10" @default.
• W2084555720 title "AAB-Sequence Living Radical Chain Copolymerization of Naturally Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer" @default.
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• W2084555720 doi "https://doi.org/10.1021/ja1042353" @default.
• W2084555720 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20586492" @default.
• W2084555720 hasPublicationYear "2010" @default.
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