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- W2084556487 abstract "Abstract A two state molecular orbital model of poly(p-phenylene vinylene) (PPV) is solved using the density matrix renormalisation group method. The energies and spatial correlation functions of the low lying states are calculated. A band of tightly bound 1 B u − excitons and a band of charge-transfer 1 A g + excitons exist below the band gap. In the limit of infinite chains, the lowest lying 1 B u − exciton is at ca. 2.6 eV, while the lowest lying 1 A g + exciton is at ca. 2.9 eV. The band threshold is at 3.2 eV." @default.
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- W2084556487 date "1999-05-01" @default.
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- W2084556487 title "The low energy electronic structure of poly(p-phenylene vinylene)" @default.
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- W2084556487 doi "https://doi.org/10.1016/s0379-6779(98)00767-x" @default.
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