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- W2084579332 abstract "Two new Co(II) based metal-organic frameworks, namely {[Co5(μ3-OH)2(m-pda)3(bix)4]·2ClO4}n (1) and {[Co2(p-pda)2(bix)2(H2O)]·H2O}n (2), were prepared by hydrothermal reactions of Co(II) salt with two isomeric dicarboxyl tectons 1,3-phenylenediacetic acid (m-pda) and 1,4-phenylenediacetic acid (p-pda), along with 1,3-bis(imidazol-L-ylmethyl)benzene (bix). Both complexes 1 and 2 have been characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). 1 shows a 6-connected 3-D pcu cationic framework with pentanuclear [Co5(μ3-OH)2(COO)6(bix)2](2+) units, while 2 exhibits a 6-connected 3-D msw net based on [Co2(μ2-H2O)(COO)2](2+) clusters. The results indicate that the different dispositions of the carboxylic groups of dicarboxylates have an important effect on the overall coordination frameworks. Perchlorate anions in 1 can be partly exchanged by thiocyanate and azide anions, however they are unavailable to nitrate anions. Magnetic susceptibility measurements indicate that both 1 and 2 show weak antiferromagnetic interactions between the adjacent Co(II) ions." @default.
- W2084579332 created "2016-06-24" @default.
- W2084579332 creator A5002804451 @default.
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- W2084579332 creator A5031591139 @default.
- W2084579332 creator A5052269140 @default.
- W2084579332 creator A5090069748 @default.
- W2084579332 date "2014-07-11" @default.
- W2084579332 modified "2023-10-10" @default.
- W2084579332 title "Positional isomeric tunable two Co(<scp>ii</scp>) 6-connected 3-D frameworks with pentanuclear to binuclear units: structures, ion-exchange and magnetic properties" @default.
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- W2084579332 doi "https://doi.org/10.1039/c4dt01086h" @default.
- W2084579332 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25190003" @default.
- W2084579332 hasPublicationYear "2014" @default.
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