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- W2084585871 abstract "Phases which are homeotypic to arsenic by replacement (R), small homogeneous deformation (D), and small inhomogeneous deformation (I), show for increasing valence electron concentration an increasing axial ratio 3¦a3¦¦a1¦NL (a, elementary cell; NL, number of layers parallel to a1, a2 per a3). They should be considered therefore to belong to a homeodesmic class, i.e. to a class of phases with similar bonding type (binding). The binding is easily understood for the prototype arsenic. Four valence electrons per arsenic atom are in a spatial correlation, the averaged correlation of which has the cell b′F̃ (i.e.b′ with a somewhat deformed face centred cubic type F) which has the commensurability a = b'F̃H(2;63) (H, hexagonal aspect of F̃). The remaining valence electrons are Hund inserted into the b' correlation and form a b″C̃H correlation (i.e. b″ with deformed cubic primitive type in hexagonal aspect) with commensurability a = b″C̃H(1;63). The peripheral d electrons are in an eH correlation (i.e.e with isometric hexagonal type H) with commensurability a = eH(√12;9). The correlations b′, b″ and e interact and influence the crystal cell and the atomic sites; in the homeotypic class they stabilize intermediate phases at certain compositions. In less close homeotypes of arsenic such as selenium the binding is modified more markedly and this change causes new homeotypisms. Also the remarkable homeotypism Se-Te finds a simple explanation. It is a surprising result of the present analysis that the b″ correlation is sometimes not perfectly commensurable with the b′ correlation." @default.
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- W2084585871 date "1986-05-01" @default.
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- W2084585871 title "On the bindings in rdi-homeotypes of arsenic" @default.
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- W2084585871 doi "https://doi.org/10.1016/0022-5088(86)90193-1" @default.
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