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- W2084604189 abstract "The reaction of zinc enolates, viz(13), derived from arylacetates with 2-aryl-3-methoxymaleic anhydrides gives β-hydroxy ester intermediates viz(17) which can be dehydrated to Z- and E- isomers of permethylated pulvinic acids. Thus, the intermediate (17) derived from (15) and (16) produces the Z- and E-isomers (23) and (24) respectively, of permethylated gomphidic acid. In a similar manner, the geometrical isomers of permethylated isogomphidic acid [(27) and (28)] and methyl leprapinate [(29) and (30)] are synthesised from appropriate arylacetate and aryl methoxymaleic anhydride precursors." @default.
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- W2084604189 date "1986-01-01" @default.
- W2084604189 modified "2023-09-23" @default.
- W2084604189 title "New syntheses of pulvinic acids via reformatsky-type reactions with aryl-methoxymaleic anhydrides" @default.
- W2084604189 doi "https://doi.org/10.1039/p19860002127" @default.
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