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- W2084636586 abstract "The thermal decomposition of ethylbenzene has been investigated under high dilution by Ar in incident and reflected shock waves in the temperature range 1250–1600 K. At 4 · 10−6 ≤ [Ar] ≤ 2.4 · 10−4 mol cm−3 the reaction was found to be in the fall-off regime of the unimolecular reaction. At the highest experimental density a first order rate constant k = 1017.1 ± 0.3 exp(–340 ± 10 kJ mol−1/RT) s−1 has been derived. Based on observations of the UV spectra of the primary dissociation fragment and the final product styrene, as well as the kinetics of formation and consumption of the intermediate species, a dominant formation of benzyl radicals can be excluded. Instead it was shown that the dissociation starts with a C–H bond split." @default.
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- W2084636586 date "1983-11-01" @default.
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- W2084636586 title "Thermal Decomposition of Ethylbenzene in Shock Waves" @default.
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- W2084636586 doi "https://doi.org/10.1002/bbpc.19830871114" @default.
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