Matches in SemOpenAlex for { <https://semopenalex.org/work/W2084648081> ?p ?o ?g. }
- W2084648081 endingPage "1387" @default.
- W2084648081 startingPage "1367" @default.
- W2084648081 abstract "The integral equation of the convolution-hypernetted chain approximation is solved numerically at five temperatures for the Lennard-Jones (12, 6) potential. Due to an inconsistency in the approximation there are two equations of state associated with it. These are compared with each other, with other theories, and with the experimental argon equation of state. At high temperatures, the two equations of state agree both with experiment and with more a priori theory at low densities and bracket them at higher densities, their mean giving a good representation of both. The integral equation is found to be singular at certain temperature—density points, their locus forming a dome shaped curve in the T—ρ plane. These points are shown to correspond to the limits of metastability in the van der Waals gas, the highest temperature point being the critical point. The nonsingular points below the critical point correspond either to a homogeneous gas (low densities) or liquid (high densities) phase. The former are in good agreement with the three-term virial series, as expected, and the latter are a considerable improvement over it. The equation of state is a considerable improvement over that obtained from the Born—Green equation by Kirkwood, Lewinson, and Alder, the latter predicting negative pressures over most of the liquid range while these results show only positive pressures. The comparisons with experiment are obscured by the inadequacy of the (12, 6) potential function. The use of temperature ``compensated'' potential parameters (as determined by the second virial coefficient) indicates that the use of a more reasonable potential function in the theory will give a relatively good representation of the equation of state of a fluid over a wide range of temperatures and densities." @default.
- W2084648081 created "2016-06-24" @default.
- W2084648081 creator A5025564857 @default.
- W2084648081 creator A5039780591 @default.
- W2084648081 date "1963-09-15" @default.
- W2084648081 modified "2023-10-16" @default.
- W2084648081 title "Numerical Solutions of the Convolution-Hypernetted Chain Integral Equation for the Pair Correlation Function of a Fluid. I. The Lennard-Jones (12, 6) Potential" @default.
- W2084648081 cites W1970973025 @default.
- W2084648081 cites W1973211772 @default.
- W2084648081 cites W1983494698 @default.
- W2084648081 cites W1996640812 @default.
- W2084648081 cites W1998815807 @default.
- W2084648081 cites W2000605679 @default.
- W2084648081 cites W2004427428 @default.
- W2084648081 cites W2005783408 @default.
- W2084648081 cites W2014281459 @default.
- W2084648081 cites W2021678430 @default.
- W2084648081 cites W2029077046 @default.
- W2084648081 cites W2029576384 @default.
- W2084648081 cites W2044747661 @default.
- W2084648081 cites W2046167980 @default.
- W2084648081 cites W2047187225 @default.
- W2084648081 cites W2047987582 @default.
- W2084648081 cites W2049700592 @default.
- W2084648081 cites W2054902762 @default.
- W2084648081 cites W2066634050 @default.
- W2084648081 cites W2071545108 @default.
- W2084648081 cites W2072784612 @default.
- W2084648081 cites W2081543739 @default.
- W2084648081 cites W2089374112 @default.
- W2084648081 cites W2092115355 @default.
- W2084648081 cites W2093230371 @default.
- W2084648081 cites W2094072738 @default.
- W2084648081 cites W2094588823 @default.
- W2084648081 cites W2121500064 @default.
- W2084648081 cites W2128407274 @default.
- W2084648081 cites W2128996435 @default.
- W2084648081 cites W2140001784 @default.
- W2084648081 cites W4233204288 @default.
- W2084648081 cites W4246214158 @default.
- W2084648081 doi "https://doi.org/10.1063/1.1734454" @default.
- W2084648081 hasPublicationYear "1963" @default.
- W2084648081 type Work @default.
- W2084648081 sameAs 2084648081 @default.
- W2084648081 citedByCount "47" @default.
- W2084648081 countsByYear W20846480812014 @default.
- W2084648081 crossrefType "journal-article" @default.
- W2084648081 hasAuthorship W2084648081A5025564857 @default.
- W2084648081 hasAuthorship W2084648081A5039780591 @default.
- W2084648081 hasConcept C119094556 @default.
- W2084648081 hasConcept C121332964 @default.
- W2084648081 hasConcept C126061179 @default.
- W2084648081 hasConcept C134306372 @default.
- W2084648081 hasConcept C135508586 @default.
- W2084648081 hasConcept C185592680 @default.
- W2084648081 hasConcept C187510041 @default.
- W2084648081 hasConcept C196298200 @default.
- W2084648081 hasConcept C27016315 @default.
- W2084648081 hasConcept C32909587 @default.
- W2084648081 hasConcept C33923547 @default.
- W2084648081 hasConcept C44280652 @default.
- W2084648081 hasConcept C53810900 @default.
- W2084648081 hasConcept C59593255 @default.
- W2084648081 hasConcept C62520636 @default.
- W2084648081 hasConcept C85906118 @default.
- W2084648081 hasConcept C93218973 @default.
- W2084648081 hasConcept C97355855 @default.
- W2084648081 hasConceptScore W2084648081C119094556 @default.
- W2084648081 hasConceptScore W2084648081C121332964 @default.
- W2084648081 hasConceptScore W2084648081C126061179 @default.
- W2084648081 hasConceptScore W2084648081C134306372 @default.
- W2084648081 hasConceptScore W2084648081C135508586 @default.
- W2084648081 hasConceptScore W2084648081C185592680 @default.
- W2084648081 hasConceptScore W2084648081C187510041 @default.
- W2084648081 hasConceptScore W2084648081C196298200 @default.
- W2084648081 hasConceptScore W2084648081C27016315 @default.
- W2084648081 hasConceptScore W2084648081C32909587 @default.
- W2084648081 hasConceptScore W2084648081C33923547 @default.
- W2084648081 hasConceptScore W2084648081C44280652 @default.
- W2084648081 hasConceptScore W2084648081C53810900 @default.
- W2084648081 hasConceptScore W2084648081C59593255 @default.
- W2084648081 hasConceptScore W2084648081C62520636 @default.
- W2084648081 hasConceptScore W2084648081C85906118 @default.
- W2084648081 hasConceptScore W2084648081C93218973 @default.
- W2084648081 hasConceptScore W2084648081C97355855 @default.
- W2084648081 hasIssue "6" @default.
- W2084648081 hasLocation W20846480811 @default.
- W2084648081 hasOpenAccess W2084648081 @default.
- W2084648081 hasPrimaryLocation W20846480811 @default.
- W2084648081 hasRelatedWork W1544314085 @default.
- W2084648081 hasRelatedWork W1985195226 @default.
- W2084648081 hasRelatedWork W2021916795 @default.
- W2084648081 hasRelatedWork W2032795482 @default.
- W2084648081 hasRelatedWork W2078734997 @default.
- W2084648081 hasRelatedWork W2084648081 @default.
- W2084648081 hasRelatedWork W2129665397 @default.
- W2084648081 hasRelatedWork W2155741946 @default.
- W2084648081 hasRelatedWork W3200115929 @default.