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- W2084654511 abstract "A two-step, generally applicable synthetic approach for nonlinear optical (NLO) side-chain polyimides was developed. This included the preparation of a preimidized, organosoluble polyimide with benzene moiety pendant from main chains, followed by the covalent bonding of the NLO chromophores onto the polyimide backbone via a post-azo-coupling reaction. The degree of functionalization of polyimides was estimated by UV-VIS spectroscopy. The glass transition temperature (Tg) of a polyimide decreased by only 10–20°C after the functionalization, which was much smaller than the decrease in Tg when the chromophores were chemically bonded to the polyimide main chains through an ether linkage using a post-Mitsunobu condensation. The solubility and thermal stability of polyimides were also studied. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 76: 290–295, 2000" @default.
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- W2084654511 date "2000-04-18" @default.
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- W2084654511 title "Synthesis and characterization of side-chain polyimides for second-order nonlinear optics via a post-azo-coupling reaction" @default.
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- W2084654511 doi "https://doi.org/10.1002/(sici)1097-4628(20000418)76:3<290::aid-app3>3.0.co;2-a" @default.
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