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- W2084667573 abstract "The optical Stark effect in the Q(1) and R(0) lines of the [15.1]1-XΣ+1 (1,0) band of rhodium mononitride (RhN) were recorded and analyzed to determine the permanent electric dipole moments μ for the XΣ+1(υ=0) and [15.1]1(υ=1) states to be 2.43(5) and 1.75(1)D, respectively. The determined dipole moments are compared to predicted values obtained from density functional theory [Stevens et al., Chem. Phys. Lett. 421, 281 (2006)] and an all-electron ab initio calculation [Shim et al., J. Mol. Struct. THEOCHEM 393, 127 (1997)]. A simple single configuration molecular orbital correlation diagram is used to rationalize the relative values of μ for the 4d mononitrides and RhO. An electronic configuration for the [15.1]1 state is proposed based on the interpretation of the Rh103 and N14 magnetic hyperfine interactions." @default.
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- W2084667573 date "2007-06-28" @default.
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- W2084667573 title "Molecular beam optical Stark study of rhodium mononitride" @default.
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- W2084667573 doi "https://doi.org/10.1063/1.2742386" @default.
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