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- W2084702982 abstract "Abstract A kind of chiral azobenzene amphiphile, N -[4-(4-dodecyloxyphenylazo)benzoyl]- l -glutamic acid (C 12 -Azo- l -Glu; as shown in Fig. 1), was synthesized and the self-organization properties on solid substrates were investigated. C 12 -Azo- l -Glu underwent a reversible trans – cis photoisomerization in dilute solution. While the photoisomerization was suppressed on solid substrate because of the H-aggregation, indicating the formation of compact film. When C 12 -Azo- l -Glu was cast from ethanol solution onto the hydrophilic surface of mica, a stable flat-layered structure formed spontaneously in large scale. High-resolution images allowed the identification of the relative orientation of molecular rows in the ordered thin film and the crystal lattice of mica. A molecular packing model of the layered structure was proposed. There was a template effect of mica to the self-organization process. Hydrogen bonding, π–π interaction and the chiral center in the molecule played the important roles in the self-organization process. The cooperative competitive effect between them led to the highly ordered structure." @default.
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- W2084702982 date "2003-12-01" @default.
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- W2084702982 title "Atomic force microscopy study of self-organization of chiral azobenzene derived from amino acid" @default.
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- W2084702982 doi "https://doi.org/10.1016/s0169-4332(03)00872-9" @default.
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