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- W2084729538 abstract "Benzoyl p-toluenesulfonyl peroxide (BTP) was decomposed in benzene, toluene, chlorobenzene, nitrobenzene, or anisole in a nitrogen or oxygen atmosphere. Yields of aryl benzoates and p-toluenesulfonates were always greater in an oxygen atmosphere than those in a nitrogen atmosphere, except those with nitrobenzene. The isomer distributions of these aryl benzoates and p-toluenesulfonates were determined. The rate of decomposition in anisole was considerably greater than those in other arenes. When BTP[carbonyl-18O] was decomposed in anisole, the o- or p-anisyl benzoate formed was found to contain about equal amounts of oxygen-18 at both the carbonyl and phenoxy oxygens. On the basis of these findings the mechanisms of benzoyloxylation and p-toluenesulfonyloxylation were discussed." @default.
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- W2084729538 date "1972-09-01" @default.
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- W2084729538 title "Aroyl Arenesulfonyl Peroxides. VI. Benzoyloxylation and<i>p</i>-Toluenesulfonyloxylation of Aromatic Compounds with Benzoyl<i>p</i>-Toluenesulfonyl Peroxide" @default.
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- W2084729538 doi "https://doi.org/10.1246/bcsj.45.2902" @default.
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