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- W2084745652 abstract "Volume changes at the valence phase transition occur as a macroscopic mechanical instability, where only a single mode representing homogeneous expansion becomes unstable without critical phonon enhancement. As a consequence, the Landau theory of phase transitions holds exactly at the critical point in describing the transition phenomenologically. However, there is a new possibility: If crystals are allowed to change their shapes in only one direction, the acoustic mode in that direction can become critical at the transition. We examine macroscopic dynamics near the transition and point out the resemblance between the valence transition and the swelling transition in gels. The frequency-dependent specific heat is also proposed." @default.
- W2084745652 created "2016-06-24" @default.
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- W2084745652 date "1989-06-01" @default.
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- W2084745652 title "Volume-change phase transition in solids at valence instability" @default.
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- W2084745652 doi "https://doi.org/10.1103/physrevb.39.12308" @default.
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