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• W2084829073 abstract "Abstract The tunneling-rotation spectrum of the ground state of the hydrogen fluoride dimer, HF⋯HF, has been extended to the submillimeter wavelength region with the RAD-3 submillimeter spectrometer at Gorky in the frequency range 180–380 GHz at 210 K and pressures from 0.5 to 1.5 Torr. The spectrum has been reinvestigated at lower frequencies with a conventional Stark spectrometer at pressures between 0.1 to 0.2 Torr at the National Institute of Standards and Technology. Lines of the a -type K = 3 subband have been observed for the first time. The tunneling frequency for the K = 3 state is 114 306.35(53) MHz. The rotational constants of this subband are somewhat anomalous as compared with those for the lower K sublevels. For example, the B rotational constant for the B u state is larger than that for the A g state, while for all the lower K sublevels the opposite is true. Higher- J R - and P -branch lines of the K = 0 through K = 2 subbands have been identified and improved rotational constants for these states have been obtained. An atlas of all a - and b -type far infrared and microwave ground state tunneling-rotation transitions for K up to 3 giving frequency, uncertainty, and relative intensity has been prepared." @default.
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• W2084829073 date "1990-06-01" @default.
• W2084829073 modified "2023-10-03" @default.
• W2084829073 title "Tunneling-rotation spectrum of the hydrogen fluoride dimer" @default.
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• W2084829073 doi "https://doi.org/10.1016/0022-2852(90)90158-m" @default.
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